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S  0 ``  X*  0 `   Z*  0 `   Z*z  bA޽h @ ?Parchment ̙33 Default Design 0 zr@ ( )   0 x P    P*    0}     R*  d  c $ ?    0r  @  RClick to edit Master text styles Second level Third level Fourth level Fifth level!     S  6d `P   P*    6$ `   R*  H  0޽h ? ̙3380___PPT10.;@8 0X(   $+ X X 0\ P    X*  X 0X     Z*  X 6 `P   X*  X 6D `   Z* H X 0޽h ? ̙3380___PPT10.;@m 0L0 P*(    00 +AN INTRODUCTION TO THE CHEMISTRY OF ALKANEST!(2 82 f0f<fJ  C "A KTRE: . " <̙? x @ 0 0 ( <̙? x @L 0 0 ) 0x m OKNOCKHARDY PUBLISHING(2 f * 08"`>B 2008 SPECIFICATIONS>G$G   B  s *޽h ? ̙33z  0L0   ` (  dB  <D)P0Q  0Pp@ 0 0dB @ <D)PXP  0X0@ 0 0W   0c0Pa INTRODUCTION This Powerpoint show is one of several produced to help students understand selected topics at AS and A2 level Chemistry. It is based on the requirements of the AQA and OCR specifications but is suitable for other examination boards. Individual students may use the material at home for revision purposes or it may be used for classroom teaching if an interactive white board is available. Accompanying notes on this, and the full range of AS and A2 topics, are available from the KNOCKHARDY SCIENCE WEBSITE at... www.knockhardy.org.uk/sci.htm Navigation is achieved by... either clicking on the grey arrows at the foot of each page or using the left and right arrow keys on the keyboard (2 2(2 2   75, dB   <D?     0{{0P( OKNOCKHARDY PUBLISHING(2    0lEX fTHE CHEMISTRY OF ALKANES2(2$f<fB  s *޽h ? ̙33  0L0 D < p (    0   CONTENTS Structure of alkanes Physical properties of alkanes Chemical properties of alkanes Breaking covalent bonds Chlorination via free radical substitution Cracking Revision check listV 202 2>'idB  <D)P0Q  0Pp@ 0 0dB  @ <D)PXP   0X0@ 0 0  0{mC @#  0 0  6~m( !@*  0 0  6p]3@1  0 0  6Km @8  0 0  6> ]W @?  0 0  6 m @F  0 0  6 m @M  0 0  0X fTHE CHEMISTRY OF ALKANES2(2$f<fB  s *޽h ? ̙33" 0L0 P(  "  0`Hx ^Before you start it would be helpful to& Recall the definition of a covalent bond Be able to balance simple equations Be able to write out structures for hydrocarbons H*(2 2)dB  <D)P0Q  0Pp@ 0 0dB @ <D)PXP  0X0@ 0 0  0X fTHE CHEMISTRY OF ALKANES2(2$f<fB  s *޽h ? ̙33 0L0  (  \   0Ћ 03 General members of a homologous series general formula is CnH2n+2 - for non-cyclic alkanes saturated hydrocarbons - all carbon-carbon bonding is single bonds are spaced tetrahedrally about carbon atoms. Isomerism the first example of structural isomerism occurs with C4H10 BUTANE 2-METHYLPROPANE Structural isomers have the SAME MOLECULAR FORMULA BUT DIFFERENT STRUCTURAL FORMULA They possess different physical properties such as boiling point, melting point and densityT@#`   *3':b@X  W   L dB  <D)P0Q  0Pp@ 0 0dB @ <D)PXP  0X0@ 0 0  0$q~ UALKANES2(2ffJ  C "A but19 w J  C "A but2i E B  s *޽h ? ̙33 0L0 //TH(  TdB T <D)P0Q T 0Pp@ 0 0dB T@ <D)PXP T 0X0@ 0 0 T 0 gHYBRIDISATION OF ORBITALS2(2f3{ T s *>?{  !;The electronic configuration of a carbon atom is 1s22s22p2 <13333333 < >`@F y" !  T " N W 3  T yE ! fB  T 6Df>fB  T 6Dok lB  T <D~  T N??M W # T 0>W+ C1&(2 T 0<>_)3 F1s((2#N ;  T y" fB T 6Do: : fB T 6Df> n fB T 6DoV X lB T <Dn sV lB T <Dn: l ~ T N?? T  P x  T#  ~ T N?? P + ~ T N??+P  ~ T N??P x  T 0h;V *  C2&(2 T 0 >   F2s((2 T 0@#>   F2p((28T Zo T# @v X fB T 6DooofB  TB 6DoZo8T Zo !T# v  fB "T 6DooofB #TB 6DoZo8T Zo $T# @VXfB %T 6DooofB &TB 6DoZo8T Zo 'T# VfB (T 6DooofB )TB 6DoZo8T Zo *T# H .` fB +T 6DooofB ,TB 6DoZo8T Zo -T#  . fB .T 6DooofB /TB 6DoZoB T s *޽h ? ̙33. 0L0 --YYX0-(  XdB X <D)P0Q X 0Pp@ 0 0dB X@ <D)PXP X 0X0@ 0 0 X 00> gHYBRIDISATION OF ORBITALS2(2f3{ X s *5>?{  !;The electronic configuration of a carbon atom is 1s22s22p2 <13333333 < >`@F y" !  X " N W 3  X yE ! fB  X 6Df>fB  X 6Dok lB  X <D~  X N??M W # X 0|:>W+ C1&(2 X 0,I>_)3 F1s((2#N ;  X y" fB X 6Do: : fB X 6Df> n fB X 6DoV X lB X <Dn sV lB X <Dn: l ~ X N?? T  P x  X#  ~ X N?? P + ~ X N??+P  ~ X N??P x  X 0P>;V *  C2&(2 X 08U>   F2s((2 X 0Y>   F2p((28T Zo X# @v X fB X 6DooofB  XB 6DoZo8T Zo !X# v  fB "X 6DooofB #XB 6DoZo8T Zo $X# @VXfB %X 6DooofB &XB 6DoZo8T Zo 'X# VfB (X 6DooofB )XB 6DoZo8T Zo *X# H .` fB +X 6DooofB ,XB 6DoZo8T Zo -X#  . fB .X 6DooofB /XB 6DoZo 0X s *q>?u{  cIf you provide a bit of energy you can promote (lift) one of the s electrons into a p orbital. The configuration is now 1s22s12p3 y333333  >`@F O '  1X O  N W 3 2X O K ' fB 3X 6Df>fB 4X 6Dok lB 5X <D~ 6X N??M W # 7X 0Xj>W+ C1&(2 8X 0y>_)3 F1s((2#N ;  9X O fB :X 6Do: : fB ;X 6Df> n fB X <Dn: l ~ ?X N?? T  P x  @X#  ~ AX N?? P + ~ BX N??+P  ~ CX N??P x  DX 0؀>;V *  C2&(2 EX 0>   F2s((2 FX 00>   F2p((28T Zo GX# | . fB HX 6DooofB IXB 6DoZo8T Zo JX# ]| u fB KX 6DooofB LXB 6DoZo8T Zo MX# \.fB NX 6DooofB OXB 6DoZo8T Zo PX# 46fB QX 6DooofB RXB 6DoZo8T Zo SX# 4fB TX 6DooofB UXB 6DoZo8T Zo VX# z,fB WX 6DooofB XXB 6DoZo} YX s *l>?Y #wThe process is favourable because the of arrangement of electrons; four unpaired and with less repulsion is more stable`x 3A3 3 x >`@B X s *޽h ? ̙33" 0L0 !!DD\L!(  \j \ B?N , dB \ <D)P0Q \ 0Pp@ 0 0dB \@ <D)PXP \ 0X0@ 0 0 \ 0> r$HYBRIDISATION OF ORBITALS IN ALKANES2%(2$f3J \ C "A  orbp J  \ C "A orbs  '   \ s *>?gX0 0The four orbitals (an s and three p s) combine or HYBRIDISE to give four new orbitals. All four orbitals are equivalent. Because one s and three p orbitals are used, it is called sp3 hybridisation 2 3  3:3     (     ,  + >`@0L Zo  \#  ]{ fB  \ 6DooofB  \B 6DoZoj \ B?O  j \ B?N  j \ B?N  0L Zo \#  y fB \ 6DooofB \B 6DoZo0L Zo \#   fB \ 6DooofB \B 6DoZo0L Zo \#   fB \ 6DooofB \B 6DoZoj \ B?M  0L Zo \#   z fB \ 6DooofB \B 6DoZoj \ B?N S @ j \ B?M I 6 j  \ B?M ? , 0L Zo !\#  x fB "\ 6DooofB #\B 6DoZo0L Zo $\#  t fB %\ 6DooofB &\B 6DoZo0L Zo '\#  h fB (\ 6DooofB )\B 6DoZoj *\ B?E yf 0L Zo +\#  r fB ,\ 6DooofB -\B 6DoZoj .\ B?F  j /\ B?E $ j 0\ B?E | 0L Zo 1\#  (p fB 2\ 6DooofB 3\B 6DoZo0L Zo 4\#  Ovz fB 5\ 6DooofB 6\B 6DoZo0L Zo 7\#  { fB 8\ 6DooofB 9\B 6DoZovB :\ ND>? S6 vB ;\ ND>?   <\ s *>?#  2s22p2P  3  >`@ =\ s *>?6   2s12p3P  3  >`@ >\ s *>?.   4 x sp36  3  >`@J ?\ C "A  orbp t  J @\ C "A  orbp h  N A\ C &Asporbg G' N B\ C &Asporbg ' N C\ C &Asporbg T' N D\ C &Asporbg .' B \ s *޽h ? ̙33  0L0  x  `(  `dB ` <D)P0Q ` 0Pp@ 0 0dB `@ <D)PXP ` 0X0@ 0 0L ` C $A sp31g>  ` s * 0w?X  >xIn ALKANES, the four sp3 orbitals of carbon repel each other into a TETRAHEDRAL arrangement with bond angles of 109.5. `y , (3&  X >`@F  ` s *Lw?   ^Each sp3 orbital in carbon overlaps with the 1s orbital of a hydrogen atom to form a C-H bond.B_ V3 _ >`@  ` 0'w fTHE STRUCTURE OF ALKANES2(2f3N  ` C &Asp210g( P  N ` C &Asp211g( + 2 `@ S C xENGZYHGJ^QQԔ? `TUJ x`TUJ x^QUJ x^Q y  ` s *Lw?Y -  n109.5  >`@B ` s *޽h ?` ̙33  0L0   H2 (  H H 00Vw X0/ 0Boiling point increases as they get more carbon atoms in their formula more atoms = greater intermolecular Van der Waals forces greater intermolecular force = more energy to separate the molecules greater energy required = higher boiling point CH4 (-161C) C2H6 (-88C) C3H8 (-42C) C4H10 (-0.5C) difference gets less - mass increases by a smaller percentage  @ 333 33333 33333 333333A@s     dB H <D)P0Q H 0Pp@ 0 0dB H@ <D)PXP H 0X0@ 0 0  H 0rwq~ lPHYSICAL PROPERTIES OF ALKANES2(2ffB H s *޽h ? ̙33y___PPT10Y+D=' = @B +d 0L0 skp x (  x x 0dXw X0L 6Boiling point increases as they get more carbon atoms in their formula more atoms = greater intermolecular Van der Waals forces greater intermolecular force = more energy to separate the molecules greater energy required = higher boiling point CH4 (-161C) C2H6 (-88C) C3H8 (-42C) C4H10 (-0.5C) difference gets less - mass increases by a smaller percentage Straight chains molecules have greater interaction than branched  The greater the branching, the lower the boiling point $@AH @:H  >@ff393@s      x 0\xwq~ lPHYSICAL PROPERTIES OF ALKANES2(2ffX x 0 -AP  x C (Apentane P R  x C *A2methbut # d  x C .Adimethprop"`! $  x 0w'P 2HIGHEST BOILING POINT LOWEST BOILING POINTb3 2$ 3   x 0Xw Bx  STRUCTURAL ISOMERS OF C5H12Z(2  dB x <D)P0Q x 0Pp@ 0 0dB x@ <D)PXP x 0X0@ 0 0B x s *޽h ? ̙33y___PPT10Y+D=' = @B + 0L0 Ppn(  p: p 0xw X01 Melting point general increase with molecular mass the trend is not as regular as that for boiling point. Solubility alkanes are non-polar so are immiscible with water they are soluble in most organic solvents.@ `     &y  Y dB p <D)P0Q p 0Pp@ 0 0dB p@ <D)PXP p 0X0@ 0 0 p 0Twq~ lPHYSICAL PROPERTIES OF ALKANES2(2ffB p s *޽h ? ̙33y___PPT10Y+D=' = @B +m 0L0 |t ( w   0w X0 ~ Introduction - fairly unreactive; (old family name, paraffin, meant little reactivity) - have relatively strong, almost NON-POLAR, SINGLE covalent bonds - they have no real sites that will encourage substances to attack them Combustion - make useful fuels - especially the lower members of the series - react with oxygen in an exothermic reaction complete CH4(g) + 2O2(g)   > CO2(g) + 2H2O(l) combustion incomplete CH4(g) + 1O2(g)   > CO(g) + 2H2O(l) combustion the greater the number of carbon atoms, the more energy produced BUT the greater the amount of oxygen needed for complete combustion. Handy tip When balancing equations involving complete combustion, remember... every carbon in the original hydrocarbon gives one carbon dioxide and every two hydrogen atoms gives a water molecule. Put the numbers into the equation, count up the O s and H s on the RHS of the equation then balance the oxygen molecules on the LHS. J f33L r 333333 333  3333333 GD #A/3&    dB  <D)P0Q  0Pp@ 0 0dB @ <D)PXP  0X0@ 0 0   0Dq~ lCHEMICAL PROPERTIES OF ALKANES2(2ffB  s *޽h ? ̙33y___PPT10Y+D=' = @B +Y 0L0     ( w dB  <D)P0Q  0Pp@ 0 0dB @ <D)PXP  0X0@ 0 0h   04 X  Processes involving combustion give rise to a variety of pollutants... power stations SO2 emissions produce acid rain internal combustion engines CO, NOx and unburnt hydrocarbons Removal SO2 react effluent gases with a suitable compound (e.g. CaO) CO and NOx pass exhaust gases through a catalytic converter Catalytic converters In the catalytic converter ... CO is converted to CO2 NOx are converted to N2 Unburnt hydrocarbons are converted to CO2 and H2O e.g. 2NO + 2CO    > N2 + 2CO2 " catalysts are made of finely divided rare metals Rh, Pd, Pt " leaded petrol must not pass through the catalyst as the lead deposits on the catalyst s surface and  poisons it, thus blocking sites for reactions to take place.*GH@G3333< 32, 33 337     R               0:q~ W POLLUTION2 (2 ffB  s *޽h ? ̙33Y  0L0    ( w   0@A 0 There are 3 ways to split the shared electron pair in an unsymmetrical covalent bond. UNEQUAL SPLITTING produces IONS known as HETEROLYSIS or HETEROLYTIC FISSION EQUAL SPLITTING produces RADICALS known as HOMOLYSIS or HOMOLYTIC FISSION " If several bonds are present the weakest bond is usually broken first " Energy to break bonds can come from a variety of energy sources - heat / light " In the reaction between methane and chlorine either can be used, however... " In the laboratory a source of UV light (or sunlight) is favoured.M@  3    3     )$ M dB  <D)P0Q  0Pp@ 0 0dB @ <D)PXP  0X0@ 0 0   0aq~ eBREAKING COVALENT BONDS2(2ffL  C $A fissg@ < B  s *޽h ? ̙33q 0L0    $(  $| $ 0g 0` X TYPICAL PROPERTIES " reactive species (atoms or groups) which possess an unpaired electron " their reactivity is due to them wanting to pair up the single electron @)J  dB $ <D)P0Q $ 0Pp@ 0 0dB $@ <D)PXP $ 0X0@ 0 0  $ 0zq~ [ FREE RADICALS2(2 ffB $ s *޽h ? ̙33 0L0 }u`t(  t t 0Ā 0   TYPICAL PROPERTIES " reactive species (atoms or groups) which possess an unpaired electron " their reactivity is due to them wanting to pair up the single electron " formed by homolytic fission (homolysis) of covalent bonds " formed during the reaction between chlorine and methane " formed during thermal cracking " involved in the reactions taking place in the ozone layer$@)I :!:@        dB t <D)P0Q t 0Pp@ 0 0dB t@ <D)PXP t 0X0@ 0 0 t 0lq~ [ FREE RADICALS2(2 ffB t s *޽h ? ̙33  0L0   lK (  l l 0( X0)  Reagents chlorine and methane Conditions UV light or sunlight - heat is an alternative energy source Equation(s) CH4(g) + Cl2(g)   > HCl(g) + CH3Cl(g) chloromethane CH3Cl(g) + Cl2(g)   > HCl(g) + CH2Cl2(l) dichloromethane CH2Cl2(l) + Cl2(g)   > HCl(g) + CHCl3(l) trichloromethane CHCl3(l) + Cl2(g)   > HCl(g) + CCl4(l) tetrachloromethane Mixtures free radicals are very reactive - they are trying to pair their electron with sufficient chlorine, every hydrogen will eventually be replaced. rk8}@ > 33 3333333 33333333333 3333333 33333  C  G    !     dB l <D)P0Q l 0Pp@ 0 0dB l@ <D)PXP l 0X0@ 0 0 l 0q~ eCHLORINATION OF METHANE2(2ffB l s *޽h ? ̙333 0L0 ha(  h4 h 0 X0 Reagents chlorine and methane Conditions UV light or sunlight - heat is an alternative energy source Equation(s) CH4(g) + Cl2(g)   > HCl(g) + CH3Cl(g) chloromethane CH3Cl(g) + Cl2(g)   > HCl(g) + CH2Cl2(l) dichloromethane CH2Cl2(l) + Cl2(g)   > HCl(g) + CHCl3(l) trichloromethane CHCl3(l) + Cl2(g)   > HCl(g) + CCl4(l) tetrachloromethane Mixtures free radicals are very reactive - they are trying to pair their electron with sufficient chlorine, every hydrogen will eventually be replaced. Mechanism Mechanisms portray what chemists think is going on in the reaction, whereas an equation tells you the ratio of products and reactants. Chlorination of methane proceeds via FREE RADICAL SUBSTITUTION because the methane is attacked by free radicals resulting in hydrogen atoms being substituted by chlorine atoms. The process is a chain reaction. In the propagation step, one radical is produced for each one usedk8}@R > 33 3333333 33333333333 3333333 33333  (G  C  G    !    T dB h <D)P0Q h 0Pp@ 0 0dB h@ <D)PXP h 0X0@ 0 0 h 0 q~ eCHLORINATION OF METHANE2(2ffB h s *޽h ? ̙33  0L0   @ 8J ( w 8dB 8 <D)P0Q 8 0Pp@ 0 0dB 8@ <D)PXP 8 0X0@ 0 0  8 0-q~ eCHLORINATION OF METHANE2(2ffP  8 C (A frstep1~0b  8 040 PtInitiation Cl2   > 2Cl" RADICALS CREATED;@ 33 33 ;  8 0;P YThe single dots represent UNPAIRED ELECTRONS During initiation, the WEAKEST BOND IS BROKEN as it requires less energy. There are three possible bonds in a mixture of alkanes and chlorine. 412 348 242 Average bond enthalpy kJ mol-1 The Cl-Cl bond is broken in preference to the others as it is the weakest and requires requires less energy to separate the atoms.4-HL@IPZPx:@@P@-c/!33@    z L 8 C $A  frbeg rA B 8 s *޽h ? ̙33h  0L0   P < (  <dB < <D)P0Q < 0Pp@ 0 0dB <@ <D)PXP < 0X0@ 0 0 < 0Vq~ eCHLORINATION OF METHANE2(2ff  < 0a0W ,Propagation Cl" + CH4   > CH3" + HCl RADICALS USED and Cl2 + CH3"   > CH3Cl + Cl" then RE-GENERATED@ 333 33 3   3333 33 3  Z    D   R  < C *A frstep23a #  < 0w3 0 ;Free radicals are very reactive because they want to pair up their single electron. They do this by abstracting a hydrogen atom from methane; a methyl radical is formed The methyl radical is also very reactive and attacks a chlorine molecule A chlorine radical is produced and the whole process can start over againX<@% < B < s *޽h ? ̙33  0L0 K C ` 4( w 4dB 4 <D)P0Q 4 0Pp@ 0 0dB 4@ <D)PXP 4 0X0@ 0 0  4 0q~ eCHLORINATION OF METHANE2(2ff   4 0  Termination Cl" + Cl"   > Cl2 RADICALS REMOVED Cl" + CH3"   > CH3Cl CH3" + CH3"   > C2H6  @  33 33 333 33 3333 3333Z    (  ; T 4 C ,Afrstep456F 4 0|  Removing the reactive free radicals brings an end to the reaction. This is not very likely at the start of the reaction because of their low concentration.@  B 4 s *޽h ? ̙33 0L0 ldp 0( `v 0dB 0 <D)P0Q 0 0Pp@ 0 0dB 0@ <D)PXP 0 0X0@ 0 0  0 0,q~ eCHLORINATION OF METHANE2(2ff&  0 0ƃ  Initiation Cl2   > 2Cl" radicals created Propagation Cl" + CH4   > CH3" + HCl radicals used and Cl2 + CH3"   > CH3Cl + Cl" then re-generated Termination Cl" + Cl"   > Cl2 radicals removed Cl" + CH3"   > CH3Cl CH3" + CH3"   > C2H6 NW@  33 33  3 3333 3 33 33 33 3   33 33  333 33 3333 3333K  #  A  .    +  <   0 00 dOVERVIEW, H    0 00 0# {Summary Due to lack of reactivity, alkanes need a very reactive species to persuade them to react Free radicals need to be formed by homolytic fission of covalent bonds This is done by shining UV light on the mixture (heat could be used) Chlorine radicals are produced because the Cl-Cl bond is the weakest You only need one chlorine radical to start things off With excess chlorine you get further substitution and a mixture of chlorinated products<@3Z#  [      B 0 s *޽h ? ̙33 0L0 f^ ,( w ,5 , 08  1Initiation Propagation Terminationt%@PZ @   2 dB , <D)P0Q , 0Pp@ 0 0dB ,@ <D)PXP , 0X0@ 0 0  , 0<q~ eCHLORINATION OF METHANE2(2ffL  , C $A frallB  , <t RADICALS PRODUCEDL@33 M , <#q RADICALS USED AND REGENERATED@333 3  , <`." u  tRADICALS REMOVED,@3 B , s *޽h ? ̙335 0L0  @c( 4k @6 @ 05.0 Further propagation If excess chlorine is present, further substitution takes place The equations show the propagation steps for the formation of... dichloromethane Cl" + CH3Cl   > CH2Cl" + HCl Cl2 + CH2Cl"   > CH2Cl2 + Cl" trichloromethane Cl" + CH2Cl2   > CHCl2" + HCl Cl2 + CHCl2"   > CHCl3 + Cl" tetrachloromethane Cl" + CHCl3   > CCl3" + HCl Cl2 + CCl3"   > CCl4 + Cl" Mixtures Because of the many possible reactions there will be a mixture of products. Individual haloalkanes can be separated by fractional distillation.@8PnZ@J3 3P 333 333 333333 33333 33333 33 333 33 33 33 33 33 333 33 33 3&$D  "  4        "  4           6  p   . dB @ <D)P0Q @ 0Pp@ 0 0dB @@ <D)PXP @ 0X0@ 0 0  @ 0@q~ eCHLORINATION OF METHANE2(2ffB @ s *޽h ? ̙33_  0L0  ( w  c   0p   Involves the breaking of C-C bonds in alkanes Converts heavy fractions into higher value products THERMAL proceeds via a free radical mechanism CATALYTIC proceeds via a carbocation (carbonium ion) mechanism@h3% 34Z.         dB   <D)P0Q   0Pp@ 0 0dB  @ <D)PXP   0X0@ 0 0   0q~ VCRACKING2 (2ff   0xP  lTHERMAL HIGH PRESSURE ... 7000 kPa HIGH TEMPERATURE ... 400C to 900C FREE RADICAL MECHANISM HOMOLYTIC FISSION PRODUCES MOSTLY ALKENES ... e.g. ETHENE for making polymers and ethanol PRODUCES HYDROGEN ... used in the Haber Process and in margarine manufacture Bonds can be broken anywhere in the molecule by C-C bond fission or C-H bond fissionHe@3     5@"     B   s *޽h ? ̙33  0L0  dN(  dc d 0ܻ   Involves the breaking of C-C bonds in alkanes Converts heavy fractions into higher value products THERMAL proceeds via a free radical mechanism CATALYTIC proceeds via a carbocation (carbonium ion) mechanism@h3% 34Z.         dB d <D)P0Q d 0Pp@ 0 0dB d@ <D)PXP d 0X0@ 0 0  d 0Έq~ VCRACKING2 (2ff  d 0҈xP eCATALYTIC SLIGHT PRESSURE HIGH TEMPERATURE ... 450C ZEOLITE CATALYST CARBOCATION (IONIC) MECHANISM HETEROLYTIC FISSION PRODUCES BRANCHED AND CYCLIC ALKANES, AROMATIC HYDROCARBONS USED FOR MOTOR FUELS ZEOLITES are crystalline aluminosilicates; clay like substances  H@     ;  A&   B d s *޽h ? ̙33Z  0L0     (    0h JREVISION CHECK (2f  0 ZWhat should you be able to do? (2x   0w- hRecall and explain the physical properties of alkanes Recall the use of alkanes as fuels Recall and explain the different ways to break a covalent bond Write balanced equations representing combustion and chlorination Understand the conditions and mechanism of free radical substitution Recall the conditions and products from thermal and catalytic cracking`i 2fffff$ffffffff,ff?f f<ffAf,.   0   ~,CAN YOU DO ALL OF THESE? YES NO6- 2!    0 H @P 0 0   0f h @U 0 0dB   <D)P0Q  0Pp@ 0 0dB @ <D)PXP  0X0@ 0 0H  0޽h ? ̙33 0L0  ;(  9  0  YYou need to go over the relevant topic(s) again Click on the button to return to the menudG(282/$f f) f  s * x  P @S 0 0dB  <D)P0Q  0Pp@ 0 0dB @ <D)PXP   0X0@ 0 0H  0޽h ? ̙33 0L0  D(    0T&xK (WELL DONE! Try some past paper questions@)(2 <fffdB  <D)P0Q  0Pp@ 0 0dB  @ <D)PXP   0X0@ 0 0H  0޽h ? ̙33 0L0 H@@(   X @dB  @@ <D)PXP @ 0X0@ 0 0 @ <̙? x @D 0 0J @ C "A KTRE: . @ 00x m h. 2008 JONATHAN HOPTON & KNOCKHARDY PUBLISHING/(2/ f @ 04fM  STHE END0(2f<f @ 09 +AN INTRODUCTION TO THE CHEMISTRY OF ALKANEST!(2 82 f0f<fH @ 0޽h ? ̙33 0L0 ph ( w     0 0M   In the past, most important organic chemicals were derived from coal. Nowadays, natural gas and crude petroleum provide an alternative source. the composition of crude petroleum varies according to its source it is a dark coloured, viscous liquid consists mostly of alkanes with up to 40 carbon atoms, plus water, sulphur and sand can be split up into fractions by fractional distillation distillation separates the compounds according to their boiling point at each level a mixture of compounds in a similar boiling range is taken off rough fractions can then be distilled further to obtain narrower boiling ranges some fractions are more important - usually the lower boiling point ones high boiling fractions may be broken down into useful lower boiling ones - CRACKING&@&   dB   <D)P0Q   0Pp@ 0 0dB  @ <D)PXP   0X0@ 0 0   0q~ \PETROCHEMICALS2(2ffB   s *޽h ? ̙33  0L0 , $  P(  PX P 0B bBoiling C s per Name of Use(s) range / C molecule fraction < 25 1 - 4 LPG (Liquefied Calor Gas Petroleum Gas) Camping Gas 40-100 4 - 12 GASOLINE Petrol 100-150 7 - 14 NAPHTHA Petrochemicals 150-200 11 - 15 KEROSINE Aviation Fuel 220-350 15 - 19 GAS OIL Central Heating Fuel > 350 20 - 30 LUBRICATING OIL Lubrication Oil > 400 30 - 40 FUEL OIL Power Station Fuel Ship Fuel > 400 40 - 50 WAX, GREASE Candles Grease for bearings > 400 > 50 BITUMEN Road surfaces RoofingL2@(PFJ@PPPF"@P+@P*@P1@P2@P.@PPP%@PZPF2@Z  &{   dB P@ <D)PXP P 0X0@ 0 0  P 0`q~ \PETROCHEMICALS2(2ffR  P C *A distowerdB P s *޽h ? ̙33r@)L!N%OC  8K/I@+ٱ `=GR\kGtRjΘXx,SfyUOh+'0T hp   No Slide TitleHOPTONJONATHAN HOPTON626Microsoft PowerPoint@Lp@@hNx@4GSg  )'    """)))UUUMMMBBB999|PP3f333f3333f3ffffff3f̙3ff333f333333333f33333333f33f3ff3f3f3f3333f33̙33333f333333f3333f3ffffff3f33ff3f3f3f3fff3ffffffffff3ffff̙fff3fffff3fff333f3f3ff3ff33f̙̙3̙ff̙̙̙3f̙3f333f3333f3ffffff3f̙3f3f3f333f3333f3ffffff3f̙3f3ffffffffff!___www4'A x(xKʦ 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